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  • 1 # 使用者1702984695764

    H2O +LiPF6 → POF3 +LiF + 2HFLiPF6→ LiF + PF5H2O+ PF5 → POF3+ 2HFH2O + POF3→ PO2F + 2HF2H2O + PO2F → H3PO4+ HFH2O + (CH2O CO2 Li) 2→ Li2CO3 + CO↑RO CO2 Li + HF→ ROCO2H + LiFLi2 CO3+2HF → H2CO3+ 2LiFLiPF5 → LiF+ PF5PF5+ H2O → 2HF + POF3C4H8O3(EMC)+ PF5 → C2H5OCOOPF4 + HF+ C2H6↑Li2CO3+ 2HF → 2LiF + H2O + CO2↑DEC + e + 2Li+ →C2H5OCO2Li (s) + CH3 • DEC + e + 2Li+ →C2H5OLi (s) + C2H5CO2• C2H5CO2• + CH3•→CH3OCO2CH3CH3 •+ 1/2H2 • →CH4↑CH3•+ CH3•→ C2H6 ↑DEC + 2e + 2Li+→C2H5OLi (s)+CO↑

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