金屬單質(Na,Al)的還原性
2Na+H2===2NaH
4Na+O2===2Na2O
2Na2O+O2===2Na2O2
2Na+O2===Na2O2
2Na+S===Na2S(爆炸)
2Na+2H2O===2NaOH+H2
2Na+2NH3===2NaNH2+H2
4Na+TiCl4(熔融)===4NaCl+Ti
2Al+3Cl2===2AlCl3
4Al+3O2===2Al2O3(鈍化)
4Al(Hg)+3O2+2xH2O===2(Al2O3.xH2O)+4Hg
4Al+3MnO2===2Al2O3+3Mn
2Al+Cr2O3===Al2O3+2Cr
2Al+Fe2O3===Al2O3+2Fe
2Al+3FeO===Al2O3+3Fe
2Al+6HCl===2AlCl3+3H2
2Al+3H2SO4===Al2(SO4)3+3H2
2Al+6H2SO4(濃)===Al2(SO4)3+3SO2+6H2O
(Al,Fe在冷,濃的H2SO4,HNO3中鈍化)
Al+4HNO(稀)===Al(NO3)3+NO+2H2O
2Al+2NaOH+2H2O===2NaAlO2+3H2
不穩定性:
2Al(OH)3===Al2O3+3H2O
酸性:
2NH3+2Na==2NaNH2+H2
(NaNH2+H2O===NaOH+NH3) 2Al + 2NaOH + 2H2O === 2NaAlO2 + 3H2(上升)
2FeCl3+2Al+3H2O=2Fe(OH)3+3H2+2AlCl3
2al + 3h2so4 === al2(so4)3 + 3h2↑ 鋁稀鹽酸反應:2al + 6hcl === 2alcl3 + 3h2↑
Al+4HNO3=Al(NO3)3+NO↑+2H2O
2 AlCl3 + 3 K2CO3 + 3 H2O===6 KCl + 2 Al(OH)3 + 3 CO2
AlCl3 + 3NaOH === Al(OH)3↓ +3NaCl
Al(OH)3 + NaOH === NaAlO2 + 2H2O
2Al + 2NaOH + 2H2O === 2NaAlO2 + 3H2↑
AlCl3 + 3NaAlO2 +6H2O === 4Al(OH)3↓
AlCl3 + 3NaHCO3 === Al(OH)3↓ + 3CO2↑ +3NaCl
反應1:2AL+6H2O=2AL(OH)3+3H2,
反應2:AL(OH)3+NaOH=NaALO2+2H2O
所以總的反應為:2Al + 2NaOH + 2H2O === 2NaAlO2 + 3H2
金屬單質(Na,Al)的還原性
2Na+H2===2NaH
4Na+O2===2Na2O
2Na2O+O2===2Na2O2
2Na+O2===Na2O2
2Na+S===Na2S(爆炸)
2Na+2H2O===2NaOH+H2
2Na+2NH3===2NaNH2+H2
4Na+TiCl4(熔融)===4NaCl+Ti
2Al+3Cl2===2AlCl3
4Al+3O2===2Al2O3(鈍化)
4Al(Hg)+3O2+2xH2O===2(Al2O3.xH2O)+4Hg
4Al+3MnO2===2Al2O3+3Mn
2Al+Cr2O3===Al2O3+2Cr
2Al+Fe2O3===Al2O3+2Fe
2Al+3FeO===Al2O3+3Fe
2Al+6HCl===2AlCl3+3H2
2Al+3H2SO4===Al2(SO4)3+3H2
2Al+6H2SO4(濃)===Al2(SO4)3+3SO2+6H2O
(Al,Fe在冷,濃的H2SO4,HNO3中鈍化)
Al+4HNO(稀)===Al(NO3)3+NO+2H2O
2Al+2NaOH+2H2O===2NaAlO2+3H2
不穩定性:
2Al(OH)3===Al2O3+3H2O
酸性:
2NH3+2Na==2NaNH2+H2
(NaNH2+H2O===NaOH+NH3) 2Al + 2NaOH + 2H2O === 2NaAlO2 + 3H2(上升)
2FeCl3+2Al+3H2O=2Fe(OH)3+3H2+2AlCl3
2al + 3h2so4 === al2(so4)3 + 3h2↑ 鋁稀鹽酸反應:2al + 6hcl === 2alcl3 + 3h2↑
Al+4HNO3=Al(NO3)3+NO↑+2H2O
2 AlCl3 + 3 K2CO3 + 3 H2O===6 KCl + 2 Al(OH)3 + 3 CO2
AlCl3 + 3NaOH === Al(OH)3↓ +3NaCl
Al(OH)3 + NaOH === NaAlO2 + 2H2O
2Al + 2NaOH + 2H2O === 2NaAlO2 + 3H2↑
AlCl3 + 3NaAlO2 +6H2O === 4Al(OH)3↓
AlCl3 + 3NaHCO3 === Al(OH)3↓ + 3CO2↑ +3NaCl
反應1:2AL+6H2O=2AL(OH)3+3H2,
反應2:AL(OH)3+NaOH=NaALO2+2H2O
所以總的反應為:2Al + 2NaOH + 2H2O === 2NaAlO2 + 3H2